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JEE Advanced Chemistry: The p-Block Elements questions with solutions

349 questions with worked solutions.

Questions

Q1. What is formed when an excess amount of sodium hydroxide is added to a solution of stannous chloride?

  1. Sn(OH)2
  2. SnO2 and H2O
  3. Na2SnO2
  4. No reaction occurs

Answer: Na2SnO2

SnCl2 first gives Sn(OH)2, which is amphoteric and dissolves in excess NaOH to form sodium stannite, Na2SnO2 (i.e. Na2[Sn(OH)4]). The product is Na2SnO2, not SnO2 + H2O, so option index 2 is correct.

Q2. Which of the following substituted silanes can form a cross-linked silicone polymer upon undergoing hydrolysis?

  1. R2Si
  2. R2SiCl2
  3. RSiCl3
  4. R3SiCl

Answer: RSiCl3

The correct option is RSiCl3 because it has three reactive chlorine atoms that can undergo hydrolysis to form a cross-linked silicone polymer, which is a characteristic of this type of silane.

Q3. Which pairs of reactants most effectively demonstrate the dual acidic and basic behavior of Al2O3.xH2O?

  1. Pair 1: Al2O3.xH2O(s) with OH⁻(aq) Pair 2: Al2O3.xH2O(s) with H2O(l)
  2. Pair 3: Al2O3.xH2O(s) with H⁺(aq) Pair 4: Al2O3.xH2O(s) with NH3(aq)
  3. Pairs 1 and 2
  4. Pairs 3 and 4

Answer: Pairs 3 and 4

Pairs 3 and 4 are correct because they demonstrate the amphoteric behavior of Al2O3.xH2O, reacting with both acids and bases to show its dual acidic and basic nature.

Q4. Among the following oxides, which one acts as the most potent oxidizing agent?

  1. Silicon dioxide (SiO2)
  2. Germanium dioxide (GeO2)
  3. Tin dioxide (SnO2)
  4. Lead dioxide (PbO2)

Answer: Lead dioxide (PbO2)

Down group 14 the +2 state becomes more stable (inert-pair effect), so the +4 oxide of lead is the strongest oxidizer, readily reduced to Pb(II). PbO2 is the most potent oxidizing agent; GeO2 (stored) is very stable. Correct option: PbO2.

Q5. Among the following compounds, which one acts as the most powerful reducing agent?

  1. Tin(II) chloride (SnCl2)
  2. Tin(IV) chloride (SnCl4)
  3. Lead(II) chloride (PbCl2)
  4. Germanium(II) chloride (GeCl2)

Answer: Tin(II) chloride (SnCl2)

Tin(II) chloride is the most powerful reducing agent because it can easily donate electrons to other substances, reducing them and itself getting oxidized in the process.

Q6. Which xenon-oxygen compound cannot be produced through the hydrolysis of xenon fluorides?

  1. XeO₂F₂
  2. XeOF₄
  3. XeO₃
  4. XeO₄

Answer: XeO₄

XeO₄ cannot be produced through the hydrolysis of xenon fluorides due to the instability and reactivity of XeO₄, which makes its formation through this method unfeasible.

Q7. When ICl2 gas is bubbled through an aqueous KI solution containing CCl4 and the mixture is agitated, what is observed?

  1. The top layer turns violet
  2. The bottom layer turns violet
  3. A uniform violet layer is produced
  4. No violet color is observed

Answer: The bottom layer turns violet

The bottom layer turns violet when ICl₂ gas is bubbled through an aqueous KI solution containing CCl₄ because the reaction between ICl₂ and KI in the presence of CCl₄ leads to the formation of a violet-colored product that settles at the bottom.

Q8. Why is concentrated H2SO4 not a good choice for reacting with solid KI to produce HI?

  1. Iodide ions are converted into iodine molecules.
  2. The resulting product is mixed with sulfur-containing impurities.
  3. Both HI and H2SO4 are classified as strong acids.
  4. While H2SO4 is a strong acid, HI is considered a weak acid.

Answer: Iodide ions are converted into iodine molecules.

Concentrated H₂SO₄ is not a good choice for reacting with solid KI to produce HI because the strong oxidizing properties of H₂SO₄ cause the iodide ions to be converted into iodine molecules, rather than forming the desired HI product.

Q9. Aluminium oxide demonstrates amphoteric behavior as it interacts with both acids and bases to produce salt and water. In the reaction Al2O3 + H2O + 2NaOH → NaAlO2 + H2O, it reacts with a base, while in the reaction Al2O3 + xH2O + HCl → AlCl3 + H2O, it reacts with an acid. What type of acid is HCl in this context?

  1. Highly basic substance
  2. Mildly acidic compound
  3. Highly acidic substance
  4. Weakly basic compound

Answer: Highly acidic substance

HCl is a highly acidic substance as it completely dissociates in water to produce H+ ions, which is characteristic of strong acids

Q10. In the reaction of diborane with water, ammonia at low temperature, and ammonia at high temperature, what is the nature of H3BO3 formed as a product?

  1. Strong base
  2. Mild acid
  3. Strong acid
  4. Mild base

Answer: Mild acid

The correct answer is that H3BO3 is a mild acid because it partially dissociates in water to release a few hydrogen ions, but not completely, resulting in a weak acidic nature.

Q11. Which of the following is classified as a strong base?

  1. Calcium oxide
  2. Silicon dioxide
  3. Tin(IV) oxide
  4. Carbon monoxide

Answer: Calcium oxide

Calcium oxide is a strong base as it completely dissociates in water to produce hydroxide ions, resulting in a high pH value.

Q12. Concentrated nitric acid, upon long standing, turns yellow-brown due to the formation of -

  1. NO
  2. NO2
  3. N2O
  4. N2O4

Answer: NO2

Concentrated nitric acid decomposes over time, forming NO₂ gas, which gives the yellow-brown color.

Q13. What is the compound obtained when white phosphorus reacts with thionyl chloride?

  1. Phosphorus trichloride
  2. Sulfuryl chloride
  3. Sulfur dichloride
  4. Phosphoryl chloride

Answer: Phosphorus trichloride

The correct answer is Phosphorus trichloride because white phosphorus reacts with thionyl chloride to produce phosphorus trichloride, sulfur dioxide, and sulfur dichloride.

Q14. What is the sequence of oxidation states of phosphorus in the compounds H₃PO₂, H₃PO₃, H₃PO₄, and H₄P₂O₆?

  1. H₃PO₄ > H₃PO₃ > H₃PO₂ > H₄P₂O₆
  2. H₃PO₄ > H₃PO₂ > H₃PO₃ > H₄P₂O₆
  3. H₃PO₂ > H₃PO₃ > H₄P₂O₆ > H₃PO₄
  4. H₃PO₄ > H₄P₂O₆ > H₃PO₃ > H₃PO₂

Answer: H₃PO₄ > H₄P₂O₆ > H₃PO₃ > H₃PO₂

The sequence of oxidation states of phosphorus in the given compounds can be determined by calculating the oxidation state of phosphorus in each compound, considering the oxidation states of hydrogen and oxygen, and then arranging them in order of decreasing oxidation state.

Q15. When potassium chlorate (KClO3) is heated with a small amount of manganese dioxide (MnO2) as a catalyst, a gas W is released. If W is allowed to react with white phosphorus, it produces a compound X. Upon treating X with concentrated nitric acid (HNO3), two products Y and Z are formed. What are Y and Z, respectively?

  1. Dinitrogen pentoxide (N2O5) and metaphosphoric acid (HPO3)
  2. Dinitrogen tetroxide (N2O4) and metaphosphoric acid (HPO3)
  3. Dinitrogen pentoxide (N2O5) and orthophosphoric acid (H3PO4)
  4. Dinitrogen trioxide (N2O3) and orthophosphoric acid (H3PO4)

Answer: Dinitrogen pentoxide (N2O5) and metaphosphoric acid (HPO3)

Potassium chlorate heated with manganese dioxide produces oxygen gas, which reacts with white phosphorus to form tetraphosphorus decaoxide. This compound then reacts with concentrated nitric acid to produce dinitrogen pentoxide and metaphosphoric acid.

Q16. When potassium chlorate is heated with a small amount of manganese dioxide as a catalyst, a gas W is produced. When W is in excess, it reacts with white phosphorus to form compound X. Upon treating X with concentrated nitric acid, compounds Y and Z are formed. What are W and X, respectively?

  1. Ozone and tetraphosphorus decaoxide
  2. Oxygen and tetraphosphorus hexoxide
  3. Oxygen and tetraphosphorus decaoxide
  4. Ozone and tetraphosphorus hexoxide

Answer: Oxygen and tetraphosphorus decaoxide

The gas W produced by heating potassium chlorate with manganese dioxide is oxygen, which then reacts with white phosphorus to form tetraphosphorus decaoxide, denoted as X.

Q17. Which of the following pairs of reactions produces the same gaseous product?

  1. (Ca3N2 + dilute HCl) and (NH4NO2 heated strongly)
  2. [(NH4)2Cr2O7 heated strongly] and (NH4NO2 heated strongly)
  3. (NH4NO3 heated strongly) and [Hg(NO3)2 heated strongly]
  4. (NH4Cl heated strongly) and [NaNO3 + Zn + aqueous NaOH heated]

Answer: [(NH4)2Cr2O7 heated strongly] and (NH4NO2 heated strongly)

Both (NH4)2Cr2O7 and NH4NO2 decompose on heating to yield N2 gas (along with water and solid Cr2O3 in the first case). No other pair in the options produces the same single gas from both reactions.

Q18. Among the four statements below about chemical reactions involving p-block and other inorganic compounds, identify the ONE that is INCORRECT: (P) The stability of dihalides follows the order: SiX2 < GeX2 < SnX2 < PbX2 (Q) The reaction 2NH3 + H2O + CO2 -> (NH4)2CO3 correctly represents ammonia absorbing carbon dioxide in water (R) When Na2CO3*10H2O is heated at a temperature below 373 K, it decomposes into Na2O, CO2, and 10H2O (S) Boric acid forms a polymeric network because of intermolecular hydrogen bonding

  1. (P) The stability of dihalides follows the order: SiX2 < GeX2 < SnX2 < PbX2
  2. (Q) The reaction 2NH3 + H2O + CO2 -> (NH4)2CO3 correctly represents ammonia absorbing carbon dioxide in water
  3. (R) When Na2CO3*10H2O is heated below 373 K, it decomposes into Na2O, CO2, and 10H2O
  4. (S) Boric acid forms a polymeric network because of intermolecular hydrogen bonding

Answer: (R) When Na2CO3*10H2O is heated below 373 K, it decomposes into Na2O, CO2, and 10H2O

Heating Na2CO3*10H2O below 373 K causes it to lose water of crystallisation (efflorescence), giving anhydrous Na2CO3 (or monohydrate), NOT Na2O and CO2; decomposition into Na2O requires very high temperatures. Statement R is therefore incorrect.

Q19. A certain compound X, when heated, produces a gas Y. The same gas Y is also produced when barium nitrate reacts with zinc in aqueous KOH solution. Identify compound X.

  1. Compound X is (NH4)2Cr2O7
  2. Compound X is NH4NO3
  3. Compound X is KNO3
  4. Compound X is NaNO3

Answer: Compound X is (NH4)2Cr2O7

(NH4)2Cr2O7 thermally decomposes in a spectacular 'volcano' reaction to give N2 gas, Cr2O3, and water. Reduction of nitrate by Zn in alkaline medium can also produce N2, linking Y = N2 to compound X = (NH4)2Cr2O7.

Q20. Count the number of specific linkages in the following species and find their sum: - m1 = number of S-S bonds in S3O9 (trithionate-type species) - m2 = number of P-P bonds in (HPO3)3 (cyclic trimetaphosphate) - m3 = number of S-S bonds in S2O8²- (peroxodisulfate ion) - m4 = number of O-O bonds in S2O6²- (dithionate ion) Find m1 + m2 + m3 + m4.

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 2

Only trithionate contributes S-S bonds (m1=2); the other species either lack the asked bond type entirely: metaphosphate has no P-P (m2=0), peroxodisulfate has no S-S (m3=0), and dithionate has no O-O (m4=0). Sum = 2.

Q21. A white waxy solid P reacts with 3 mol NaOH and 3 mol H2O to form two products Q and R. When Q is burned in oxygen (with heating), it gives product S. Given that Q is a colourless gas with a characteristic rotten-fish smell, which of the following statements about P, Q, R, and S is CORRECT?

  1. Q is also produced when H3PO4 is heated strongly
  2. P has a polymeric structure
  3. S contains only two oxygen bridges in its structure
  4. The anionic part of R contains zero acidic hydrogen atoms

Answer: The anionic part of R contains zero acidic hydrogen atoms

Q is PH3 (phosphine — colourless gas, rotten fish odour). P is P4 (white phosphorus, waxy solid). R is NaH2PO2 (sodium hypophosphite). The anion H2PO2⁻ has both H atoms on P (P-H bonds), giving zero acidic (O-H) hydrogens in the anion.

Q22. A white, colourless crystalline solid is strongly heated. A sharp crackling sound is produced, reddish-brown fumes are evolved, and the solid residue left behind is yellowish-brown. When a glowing wooden splint is introduced into the evolved fumes, it bursts into flame. The fumes are composed of:

  1. O2 only
  2. NO2 only
  3. Cl2 only
  4. NO2 and O2

Answer: NO2 and O2

Lead nitrate is a white crystalline solid that decomposes with a crackling sound (decrepitation) on heating, giving reddish-brown NO2 gas and O2 gas (which relights a glowing splint), leaving behind yellowish-brown PbO as residue.

Q23. From the list of reagents — AgNO3, BaCl2, Pb(OAc)2, HgCl2, CuSO4, SbCl3 — how many will produce a black precipitate of the metal sulphide when treated with H2S?

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 4

AgNO3 gives Ag2S (black), Pb(OAc)2 gives PbS (black), HgCl2 gives HgS (black), and CuSO4 gives CuS (black) — four black precipitates. BaCl2 gives no precipitate (BaS is soluble) and SbCl3 gives Sb2S3 which is orange.

Q24. Consider the following two statements about ionization enthalpy trends in Group 13: Statement I: The decrease in first ionization enthalpy going from B to Al is much larger than the decrease going from Al to Ga. Statement II: The 3d orbitals in gallium (Ga) are completely filled. Which of the following is the correct assessment of these statements?

  1. Statement I is incorrect but Statement II is correct.
  2. Both Statement I and Statement II are correct.
  3. Statement I is correct but Statement II is incorrect.
  4. Both Statement I and Statement II are incorrect.

Answer: Both Statement I and Statement II are correct.

Statement I is correct: IE1 drops sharply from B (~800 kJ/mol) to Al (~577 kJ/mol) but barely changes from Al to Ga (~579 kJ/mol). Statement II is correct: Ga has a completely filled 3d¹⁰ shell. The d electrons shield poorly, increasing effective nuclear charge in Ga and explaining why IE does not drop further from Al to Ga.

Q25. Which of the following statements about xenon tetrafluoride (XeF4) is/are correct?

  1. XeF4 has sp3d2 hybridisation and a square planar geometry
  2. The xenon atom in XeF4 has two lone pairs of electrons
  3. XeF4 is a non-polar molecule with zero net dipole moment
  4. All of the above

Answer: All of the above

Xe in XeF4 uses sp3d2 hybridisation (6 electron pairs: 4 bonding + 2 lone pairs). The molecule is square planar. The two lone pairs are in axial positions, mutually cancelling, so the net dipole moment is zero. XeF4 is therefore non-polar. All three individual statements are correct.

Q26. A white-coloured sodium salt is dissolved in water. The resulting solution shows neutral behaviour toward litmus. When aqueous silver nitrate is added to this solution, a white precipitate forms that is insoluble in dilute nitric acid. Identify the anion present in the salt.

  1. CO3²-
  2. Cl-
  3. SO3²-
  4. S²-

Answer: Cl-

Sodium chloride solution is neutral to litmus. AgCl is a white precipitate that does not dissolve in dilute HNO3 because HNO3 cannot shift the AgCl equilibrium (unlike Ag2CO3 or Ag2S which react with acid). The other anions either give alkaline solutions (CO3²-, S²-) or give precipitates soluble in acid (SO3²-).

Q27. Which of the following species does NOT exist in reality?

  1. ClI3
  2. XeH4
  3. BiF5
  4. Both ClI3 and XeH4

Answer: Both ClI3 and XeH4

XeH4 does not exist because hydrogen is not electronegative enough to oxidize xenon, and no Xe-H compounds are known. ClI3 does not exist because chlorine, being smaller and more electronegative than iodine, cannot act as the central atom bonded to three bulky iodine atoms. BiF5 does exist as bismuth(V) fluoride. Hence both A and B are non-existent.

Q28. Borate ion (BO3³-) is treated with concentrated H2SO4 and heated, producing compound P which gives white fumes. In a separate experiment, the same borate ion is heated with concentrated H2SO4 in the presence of ethanol (C2H5OH), producing compound Q whose vapours can be ignited with a green-edged flame. Identify P and Q respectively.

  1. P = H3BO3, Q = H3BO3
  2. P = (C2H5O)3B, Q = H3BO3
  3. P = (C2H5O)3B, Q = (C2H5O)3B
  4. P = H3BO3, Q = (C2H5O)3B

Answer: P = H3BO3, Q = (C2H5O)3B

When BO3³- reacts with concentrated H2SO4, boric acid (H3BO3) is liberated; it sublimes as white fumes. When ethanol is also present, the H3BO3 formed immediately esterifies with ethanol to give triethyl borate (C2H5O)3B, which burns with a characteristic green-bordered flame — the standard test for boron compounds.

Q29. Which of the following statements about calcium phosphite is INCORRECT?

  1. Its molecular formula is Ca3(PO3)2
  2. It contains a P–H bond
  3. The oxidation state of phosphorus in it is +3
  4. All O–P–O bond angles in it are equal

Answer: All O–P–O bond angles in it are equal

Calcium phosphite is Ca(HPO3) or Ca3(HPO3)3 depending on convention; the phosphite ion HPO3²- has the structure where P is bonded to one H, one =O (double bond or dative), and two O⁻ groups. Since one substituent is H (not O), the geometry around P is not symmetric and all O–P–O bond angles are NOT equal. Option D is therefore incorrect. The formula Ca3(PO3)2 (option A) represents the salt of phosphite PO3³-, which is less common, but the oxidation state of P is indeed +3 (option C is correct), and the P–H bond (option B) is correct for H-phosphonate type phosphite.

Q30. Which among the following are ionic carbides?

  1. CaC2
  2. Al4C3
  3. SiC
  4. Be2C

Answer: CaC2

CaC2 (calcium carbide) and Be2C (beryllium carbide) are ionic carbides. Al4C3 is also ionic (methanide type). SiC is a covalent carbide. Among the options, CaC2, Al4C3, and Be2C are ionic carbides, while SiC is not.

Q31. Which of the following chemical reactions is correct?

  1. Br⁻ + H⁺ -> HBr; then 2HBr + 2H2SO4 -> Br2 (reddish-brown) + SO2 + SO4²- + H2O
  2. 4NO3⁻ + 2H2SO4 -> 4NO2 (reddish-brown) + O2 + 2SO4²- + 2H2O
  3. SO3²- + 2H⁺ -> SO2 (colourless gas) + H2O
  4. 3I⁻ + 2H2SO4 -> I3⁻ (violet) + SO4²- + 2H2O + SO2

Answer: SO3²- + 2H⁺ -> SO2 (colourless gas) + H2O

Option C (SO3²- + 2H⁺ -> SO2 + H2O) is a correctly balanced reaction: sulphite ions reacting with acid produce sulphur dioxide gas (colourless, pungent) and water. Option A's second step is unbalanced and incorrect. Option B is missing electrons/charges — the actual reaction of NO3⁻ with H2SO4 does not produce O2. Option D's product I3⁻ is wrong (should be I2).

Q32. Which of the following anions produces a reddish-brown gas when treated with concentrated H2SO4?

  1. Br-
  2. NO3-
  3. SO3²-
  4. I-

Answer: Br-

When Br- ions react with concentrated H2SO4, the acid first forms HBr, which is then partially oxidised by the concentrated H2SO4 to give Br2 (reddish-brown gas) along with SO2. NO3- gives colourless NO2 (actually brown NO2), SO3²- gives SO2 (colourless pungent), and I- gives violet I2 vapour.

Q33. Which of the following industrial process-reaction pairs is correctly described?

  1. Ostwald process: 4NH3 + 5O2 --[Pt/Rh, 500 K, 9 bar]--> 4NO + 6H2O
  2. Contact process: S + O2 -> SO2; 2SO2 + O2 --[V2O5]--> 2SO3
  3. Deacon's process: 4HCl + O2 --[CuCl2, 723 K]--> 2Cl2 + 2H2O
  4. Haber's process: N2(g) + 3H2(g) ⇌ 2NH3(g); uses Fe/FeO catalyst and K2O/Al2O3 promoters; Mo used as promoter.

Answer: Ostwald process: 4NH3 + 5O2 --[Pt/Rh, 500 K, 9 bar]--> 4NO + 6H2O

Option A (Ostwald process) is correctly stated. Option B's stoichiometry in original was written as SO2 + 1/2 O2 which is correct but the option as written with coefficient check: 2SO2 + O2 -> 2SO3 is also correct. Option C is correct for Deacon's. Option D has an error: Mo is not used in Haber's process. Thus A, B, C are correct while D is wrong.

Q34. Three statements about halogens are given below: (P) The bond length order is F2 < Cl2 < Br2 < I2. (Q) The oxidising power order is F2 > Cl2 > Br2 > I2. (R) The correct order of bond dissociation energy is Cl2 > Br2 > F2 > I2. Which of the following is correct?

  1. P and Q are correct
  2. Q and R are correct
  3. P and R are correct
  4. P, Q and R are all correct

Answer: P and Q are correct

Bond length increases down the group (P correct). Oxidising power decreases down the group (Q correct). Standard BDE values: F2~159, Cl2~242, Br2~193, I2~151 kJ/mol, giving Cl2>Br2>F2>I2, so R is also correct. Hence all three are correct.

Q35. On heating, how many of the following compounds produce BOTH an acidic product AND a basic product simultaneously? LiNO3, CaCO3, NH4NO3, FeSO4, Mg(OH)2

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 1

LiNO3 -> Li2O (basic) + NO2 (acidic) + O2: gives both acidic and basic products. CaCO3 -> CaO (basic) + CO2 (acidic): gives both. NH4NO3 -> N2O + H2O: only neutral products. FeSO4 -> Fe2O3 + SO2 + SO3: gives acidic oxides and basic oxide. Mg(OH)2 -> MgO + H2O: only basic oxide + neutral. Careful count: LiNO3, CaCO3, and FeSO4 give both acidic and basic products = 3.

Q36. In the mineral beryl, Be3Al2Si6O18, how many oxygen atoms are shared by each SiO4 tetrahedral unit?

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 2

Beryl belongs to the cyclosilicate class with Si6O18¹²- ring anion. In this six-membered ring structure, each SiO4 tetrahedron shares two of its four oxygen atoms with neighboring tetrahedra (the two bridging oxygens), while two oxygens remain unshared (terminal). Hence, each SiO4 unit shares 2 oxygen atoms.

Q37. How many nitrate groups (NO3-) are present in one molecule of basic beryllium nitrate?

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 3

Basic beryllium nitrate is typically represented as Be4O(NO3)6, which is a tetranuclear cluster analogous to basic beryllium acetate. This formula contains 6 nitrate groups per molecule. However, if the question refers to a simpler formula unit, it could have 3 nitrate groups. The most commonly cited structure in Indian textbooks is Be4O(NO3)6 with 6 NO3.

Q38. Consider the following hydrolysis reactions: AsCl3 + excess H2O gives an oxyacid and a hydroacid. PCl3 + excess H2O gives an oxyacid and a hydroacid. PCl5 + 1 mole H2O gives an unknown product Z and HCl. The ratio of the number of pi bonds to the number of sigma bonds in compound Z is:

  1. 1:4
  2. 1:5
  3. 2:7
  4. 1:6

Answer: 1:5

PCl5 + H2O (1 mole) gives POCl3 (Z) + 2HCl. In POCl3: there is 1 P=O double bond (1 pi bond + 1 sigma bond) and 3 P-Cl single bonds (3 sigma bonds), plus the sigma component of P=O. Total sigma bonds = 1 (P=O sigma) + 3 (P-Cl) = 4, plus the coordinate/dative bond can be counted as 1 sigma = total 4 sigma bonds from P centre. Actually counting: P=O has 1 sigma + 1 pi; 3 x P-Cl each has 1 sigma. Total sigma = 4, total pi = 1. Ratio pi:sigma = 1:4. However treating the P=O as a coordinate bond (dative bond, counts as sigma), ratio is 0:4 = not listed. Using the standard Lewis structure with P=O double bond: 1 pi bond, 4 sigma bonds (1 in P=O + 3 in P-Cl). Ratio = 1:4. But considering all bonds in the molecule including O lone-pair donation, the accepted JEE answer for POCl3 is pi:sigma = 1:4.

Q39. Consider the following statements about carbides and choose the correct one(s): (I) CaC2 is an ionic carbide that produces acetylene on hydrolysis. (II) Al4C3 is an ionic carbide that produces methane on hydrolysis. (III) Be2C is an ionic carbide that produces methane on hydrolysis. (IV) SiC is a covalent carbide with an extremely high melting point. Which of the above statements are correct?

  1. (A) I and II only
  2. (B) I, II and III only
  3. (C) I, II, III and IV
  4. (D) II, III and IV only

Answer: (C) I, II, III and IV

CaC2 (calcium carbide) is an ionic acetylide: CaC2 + 2H2O -> Ca(OH)2 + C2H2 (acetylene). Al4C3 (aluminum carbide) is an ionic methanide: Al4C3 + 12H2O -> 4Al(OH)3 + 3CH4. Be2C (beryllium carbide) is an ionic methanide: Be2C + 4H2O -> 2Be(OH)2 + CH4. SiC (silicon carbide, carborundum) is a giant covalent structure with a very high melting point (~2730 deg C). All four statements are correct.

Q40. Which of the following reactions produce NO2 gas as the primary nitrogen oxide product?

  1. Cu reacting with dilute HNO3
  2. Zn reacting with dilute HNO3
  3. Zn reacting with concentrated HNO3
  4. Sn reacting with dilute HNO3

Answer: Zn reacting with concentrated HNO3

Concentrated HNO3 reacts with metals to give NO2. Zn with concentrated HNO3 gives NO2. Dilute HNO3 with most metals (Cu, Zn, Sn) gives NO, not NO2. Cu with dilute HNO3 produces NO (not NO2). So only Zn + conc. HNO3 produces NO2 among the given options.

Q41. How many p-pi to p-pi bonds are present in XeO4?

  1. 1
  2. 2
  3. 3
  4. 4

Answer: 4

XeO4 has tetrahedral geometry (4 double bonds, Xe oxidation state +8). Each Xe=O bond consists of one sigma bond and one pi bond formed by overlap of oxygen p orbital with xenon d (or p) orbital — these are p-pi to d-pi bonds. However in the context of p-pi to p-pi bonds, XeO4 is often cited to have 4 such bonds (one per Xe=O bond), using the oxygen lone pair p orbitals donated into empty Xe orbitals. Answer: 4.

Q42. An unknown salt M, when gently heated with concentrated H2SO4 and K2Cr2O7, produces reddish-brown vapours X. These vapours, when passed into NaOH solution, give a yellow solution Y. Yellow precipitate Z is formed on adding Pb(OAc)2 in acetic acid to Y. Based on this reaction scheme, the salt(s) M could be:

  1. AgCl
  2. NH4Cl + NaBr
  3. NaBr
  4. Ca(ClO4)2

Answer: NaBr

X is Br2 (reddish-brown vapour). Br2 + NaOH -> NaBr + NaBrO3 (yellow solution Y). NaBrO3/NaBr + Pb(OAc)2 -> PbBr2 (yellow precipitate Z). This is the bromine test. So M must be a bromide salt: NaBr (option C). NH4Cl+NaBr mixture would also give Br2, but the primary salt listed is NaBr. AgCl has no bromine; Ca(ClO4)2 has no bromine.

Q43. An unknown compound gives a positive chromyl chloride test and forms a blue solution with potassium ferrocyanide [K4Fe(CN)6]. Identify the compound.

  1. NaCl
  2. FeBr3
  3. CuCl2
  4. FeCl3

Answer: FeCl3

Two tests must both be positive: (1) Chromyl chloride test: positive only for chloride (Cl-) compounds — NaCl, CuCl2, FeCl3 pass; FeBr3 fails. (2) Blue color with potassium ferrocyanide K4Fe(CN)6: Fe3+ gives Prussian blue; Cu2+ gives chocolate/brown precipitate (not blue). Therefore FeCl3 satisfies both: it contains Cl- (chromyl chloride test positive) and Fe3+ (blue with K4Fe(CN)6). However, looking at the answer choices and the classic JEE question format, CuCl2 is often cited — but the correct chemistry points to FeCl3. Wait: Cu2+ + K4Fe(CN)6 gives a chocolate brown precipitate (Cu2[Fe(CN)6]). Fe3+ + K4Fe(CN)6 gives Prussian blue (Fe4[Fe(CN)6]3). So the correct answer is FeCl3.

Q44. Which of the following correctly represents the structure of peroxodisulfuric acid (H2S2O8)?

  1. HO-S(=O)2-SH
  2. HO-S(=O)2-S(=O)2-OH
  3. HO-S(=O)2-S(=O)2-S(=O)2-OH
  4. HO-S(=O)2-O-O-S(=O)2-OH

Answer: HO-S(=O)2-O-O-S(=O)2-OH

Peroxodisulfuric acid (Marshall's acid, H2S2O8) has the structure: HO-S(=O)2-O-O-S(=O)2-OH. Each sulfur is surrounded by four oxygens (two =O, one -OH, one -O- of the peroxide bridge). The characteristic feature is the -O-O- (peroxide) bond connecting the two SO3(OH) units.

Q45. Arrange the following oxides in the correct order of increasing acidic strength: SO2, P2O3, SiO2, Al2O3.

  1. SO2 > P2O3 > SiO2 > Al2O3
  2. P2O3 > SO2 > SiO2 > Al2O3
  3. P2O3 > Al2O3 > SO2 > SiO2
  4. Al2O3 > SiO2 > P2O3 > SO2

Answer: SO2 > P2O3 > SiO2 > Al2O3

Across period 3, acidic strength of oxides increases from left to right. Al2O3 is amphoteric (least acidic here), SiO2 is a weak acid oxide, P2O3 is a moderate acid oxide, and SO2 is a stronger acid oxide (dissolves in water to give H2SO3). So increasing order of acidic strength: Al2O3 < SiO2 < P2O3 < SO2, i.e., SO2 > P2O3 > SiO2 > Al2O3.

Q46. Which of the following compounds gives ONLY basic products on hydrolysis?

  1. Mg3N2
  2. NCl3
  3. BBr3
  4. PCl5

Answer: Mg3N2

Mg3N2 + 6H2O → 3Mg(OH)2 + 2NH3. Both Mg(OH)2 (basic) and NH3 (basic) are basic products only. NCl3 + 3H2O → NH3 + 3HOCl (hypochlorous acid is acidic). BBr3 + 3H2O → H3BO3 (weakly acidic) + 3HBr (acidic). PCl5 + 4H2O → H3PO4 (acidic) + 5HCl (acidic). Therefore only Mg3N2 gives exclusively basic products.

Q47. Which of the following thermal decomposition reactions is written incorrectly?

  1. Pb(NO3)2 -> PbO2 + 2NO2 + O2/2 (on heating)
  2. 2NaNO3 -> 2NaNO2 + O2 (on heating)
  3. Fe2(SO4)3 -> Fe2O3 + 3SO3 (on heating)
  4. 2NaHCO3 -> Na2CO3 + H2O + CO2 (on heating)

Answer: Pb(NO3)2 -> PbO2 + 2NO2 + O2/2 (on heating)

The correct decomposition of lead nitrate: 2Pb(NO3)2 -> 2PbO + 4NO2 + O2. PbO2 would not form under these conditions. Options B, C, D are all correct standard reactions. So option A (which gives PbO2) is wrong.

Q48. Which of the following statements about the heavier p-block elements is correct?

  1. Tl⁺ is more stable than Tl³+
  2. Pb⁴+ salts act as good oxidising agents
  3. Bi⁵+ salts act as good oxidising agents
  4. All of the above

Answer: All of the above

The inert pair effect makes the lower oxidation states of heavy p-block elements more stable. Tl⁺ is indeed more stable than Tl³+. Pb⁴+ is unstable (prefers Pb²+) so it readily accepts electrons — it is a strong oxidising agent. Bi⁵+ is unstable (prefers Bi³+) so it is also a strong oxidising agent. All three statements are correct.

Q49. Which cation is NOT precipitated by H2S gas in either acidic medium (group II) or basic/ammoniacal medium (group IV) in qualitative analysis?

  1. Pb²+
  2. Zn²+
  3. Ag⁺
  4. Ba²+

Answer: Ba²+

Pb²+ is precipitated as PbS (black) in Group II (acidic H2S). Zn²+ is precipitated as ZnS (white) in Group IV (H2S in ammoniacal solution). Ag⁺ is typically precipitated in Group I (HCl as AgCl, white), and its sulphide Ag2S can also form in Group II. Ba²+ has a very soluble sulphide (BaS is quite soluble) and is NOT precipitated by H2S in either acidic or basic medium. Barium is separated in Group V using (NH4)2CO3. Hence Ba²+ is the answer.

Q50. Which of the following gives the correct order of acidic strength?

  1. HOF > HOCl > HOBr > HOI
  2. HClO4 > HBrO4 > HIO4
  3. LiOH < Be(OH)2 < B(OH)3 < H2CO3
  4. All of the above

Answer: All of the above

Option A: For hypohalous acids HOX, as electronegativity of X decreases (F > Cl > Br > I), the O-H bond becomes weaker (less electron withdrawal from X), so acidity decreases. HOF > HOCl > HOBr > HOI. Correct. Option B: HClO4, HBrO4, HIO4 - all are the strongest oxoacids of respective halogens. Going down group 17, central atom size increases, the O-H bond strength increases relative to element-oxygen bond; acidity of highest oxoacids decreases down the group. HClO4 > HBrO4 > HIO4. Correct. Option C: LiOH is a strong base, Be(OH)2 is amphoteric (weakly basic), B(OH)3 is a weak acid, H2CO3 is a stronger acid. So acidity order: LiOH < Be(OH)2 < B(OH)3 < H2CO3. Correct. All three are correct, so answer is All of the above.

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