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ExamsJEE AdvancedChemistry

Arrange the following oxides in the correct order of increasing acidic strength: SO2, P2O3, SiO2, Al2O3.

  1. SO2 > P2O3 > SiO2 > Al2O3
  2. P2O3 > SO2 > SiO2 > Al2O3
  3. P2O3 > Al2O3 > SO2 > SiO2
  4. Al2O3 > SiO2 > P2O3 > SO2

Correct answer: SO2 > P2O3 > SiO2 > Al2O3

Solution

Across period 3, acidic strength of oxides increases from left to right. Al2O3 is amphoteric (least acidic here), SiO2 is a weak acid oxide, P2O3 is a moderate acid oxide, and SO2 is a stronger acid oxide (dissolves in water to give H2SO3). So increasing order of acidic strength: Al2O3 < SiO2 < P2O3 < SO2, i.e., SO2 > P2O3 > SiO2 > Al2O3.

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