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ExamsJEE AdvancedChemistry

From the list of reagents — AgNO3, BaCl2, Pb(OAc)2, HgCl2, CuSO4, SbCl3 — how many will produce a black precipitate of the metal sulphide when treated with H2S?

  1. 1
  2. 2
  3. 3
  4. 4

Correct answer: 4

Solution

AgNO3 gives Ag2S (black), Pb(OAc)2 gives PbS (black), HgCl2 gives HgS (black), and CuSO4 gives CuS (black) — four black precipitates. BaCl2 gives no precipitate (BaS is soluble) and SbCl3 gives Sb2S3 which is orange.

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