Exams › NEET › Chemistry

The low electron affinity value of nitrogen is due to:

1. small size
2. high nuclear charge
3. half-filled 2p subshell
4. high metallic character

Correct answer: half-filled 2p subshell

Solution

Nitrogen has a half-filled 2p subshell (2p³), which is especially stable due to exchange energy and symmetry. Gaining an extra electron would force pairing in one orbital, increasing repulsion and making electron gain less favorable.

Related NEET Chemistry questions

• Which of the following have identical bond order? (I) \( \boldsymbol{C} \boldsymbol{N}^{-} \) (II) \( \boldsymbol{O}_{\mathbf{2}}^{-} \) \( (\|\|) N O^{+} \) \( (\mid V) C N^{+} \)
• What type of bond does \( M g \) form with \( C l ? \)
• Shape of \( C O_{2} \) is:
• The shape of \( s p^{3} d^{2} \) hybridized molecule with 2 lone pairs will be:
• The hybrid orbitals with \( 33.33 \% \) Scharacter are involved in the bonding of one of the crystalline allotropes of carbon. The allotrope is :
• In certain polar solvents \( \boldsymbol{P} \boldsymbol{C l}_{5} \) undergoes an ionisation reaction in which \( C l^{-} \) ion leaves one \( P C l_{5} \) molecule and attaches itself to another \( 2 P C l_{5} \rightleftharpoons P C l_{4}^{+}+P C l_{6}^{-} \) What are the changes in the geometrical shapes that occur in this ionisation?

⚔️ Practice NEET Chemistry free + battle 1v1 →