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ExamsNEETChemistry

The measured potential for \( M g^{2+}+2 e^{-} \rightleftharpoons M g(s) \) does not depend upon:

  1. raising the temperature
  2. increasing the concentration of \( M g^{2+} \) ions
  3. making the magnesium plate bigger
  4. purity of magnesium plate

Correct answer: making the magnesium plate bigger

Solution

For the half-cell Mg^{2+} + 2e^- ⇌ Mg(s), the electrode potential depends on ion activity and temperature. The size of the solid magnesium electrode does not enter the Nernst equation, so making the plate bigger does not change the measured potential.

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