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ExamsNEETChemistry

Among the following, the couple with most positive reduction potential is :

  1. \( M n^{+3} / M n^{+2} \)
  2. \( C r^{+3} / C r^{+2} \)
  3. \( F e^{+3} / F e^{+2} \)
  4. \( C o^{+3} / C o^{+2} \)

Correct answer: \( C o^{+3} / C o^{+2} \)

Solution

A more positive reduction potential means the +3 ion is more easily reduced to +2. Among these couples, Co(III) is especially unstable relative to Co(II), so Co^{3+} gains an electron most readily. Therefore Co^{3+}/Co^{2+} has the highest reduction potential.

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