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When liquid water transitions to water vapor at 1 atm pressure, which of the following statements is accurate?
- The enthalpy change (ΔH) equals 40630 J mol^-1.
- The entropy change (ΔS) is 108.8 J K^-1 mol^-1.
- The Gibbs free energy change (ΔG) is determined by ΔH - TΔS.
- At equilibrium, when ΔG equals zero, ΔH - TΔS also equals zero.
Correct answer: At equilibrium, when ΔG equals zero, ΔH - TΔS also equals zero.
Solution
Option D is correct because when ΔG = 0, the system is at equilibrium, and the relationship ΔH - TΔS = 0 holds true.
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