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In ammonia (NH3), the bond dipoles and the molecular dipole point in the same direction, but in nitrogen trifluoride (NF3), they point in opposite directions. This results in an increase in dipole moment for NH3 and a decrease for NF3. Why does this happen?
- The vectors are oriented in the same direction.
- The vectors are oriented in opposite directions.
- The dipole moment is diminished.
- None of these statements are correct.
Correct answer: The vectors are oriented in opposite directions.
Solution
In NH3, the bond dipoles and the lone pair dipole align in the same direction, increasing the net dipole moment. In NF3, the bond dipoles oppose the lone pair dipole, reducing the net dipole moment.
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