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ExamsNEETChemistry

Given specific conductance of the solution (κ) = 0.012 ohm⁻¹ cm⁻¹ and resistance (R) = 55 ohm. We know that cell constant = Specific conductance × Observed resistance = 0.012 × 55 = 0.66 cm⁻¹.

  1. λ°Na⁺ + λ°Cl⁻ = 126.45
  2. λ°Na⁺ + λ°Cl⁻ = 426.16
  3. λ°CH₃COO⁻ + λ°Na⁺ = 91
  4. λ°CH₃COONa = 390.71 ohm⁻¹ cm²

Correct answer: λ°CH₃COONa = 390.71 ohm⁻¹ cm²

Solution

The cell constant is calculated correctly as 0.66 cm⁻¹, and the given data aligns with the molar conductivity of CH₃COONa. Option D is consistent with the provided values.

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