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If E°Fe2+/Fe = –0.441 V and E°Fe3+/Fe2+ = +0.771 V, the standard EMF of the reaction Fe + 2Fe3+ → 3Fe2+ will be
- 1.653 V
- 1.212 V
- 0.111 V
- 0.330 V
Correct answer: 1.212 V
Solution
The standard EMF of the reaction is calculated using the formula E°cell = E°cathode - E°anode. Here, Fe3+/Fe2+ acts as the cathode (+0.771 V) and Fe2+/Fe as the anode (-0.441 V). Substituting, E°cell = 0.771 - (-0.441) = 1.212 V.
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