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Al2O3 is reduced by electrolysis at low potentials and high currents. If 4.0 × 10⁴ amperes of current is passed through molten Al2O3 for 6 hours, what mass of aluminium is produced? (Assume 100% current efficiency and At. mass of Al = 27 g mol⁻¹)
- 8.1 × 10³ g
- 2.4 × 10⁵ g
- 1.3 × 10⁴ g
- 9.0 × 10³ g
Correct answer: 8.1 × 10³ g
Solution
Using Faraday's laws of electrolysis, the mass of Al produced is calculated as: m = (Z × I × t), where Z = M / (n × F). For Al, n = 3. Substituting values: m = (27 / (3 × 96500)) × (4.0 × 10⁴) × (6 × 3600) = 8.1 × 10³ g.
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