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ExamsNEETChemistry

If ΔH is the change in enthalpy and ΔE, the change in internal energy accompanying a gaseous reaction, then

  1. ΔH is always greater than ΔE
  2. ΔH < ΔE only if the number of moles of the products is greater than the number of moles of the reactants
  3. ΔH is always less than ΔE
  4. ΔH < ΔE only if the number of moles of products is less than the number of moles of the reactants

Correct answer: ΔH < ΔE only if the number of moles of products is less than the number of moles of the reactants

Solution

The relationship between ΔH and ΔE is given by ΔH = ΔE + ΔnRT, where Δn is the change in the number of moles of gas. If the number of moles of products is less than the number of moles of reactants, Δn is negative, making ΔH < ΔE.

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