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Among LiCl, BeCl2, BCl3 and CCl4, the covalent bond character follows the order
- LiCl < BeCl2 > BCl3 > CCl4
- BeCl2 < BCl3 < CCl4 < LiCl
- LiCl < BeCl2 < BCl3 < CCl4
- LiCl > BeCl2 > BCl3 > CCl4
Correct answer: LiCl < BeCl2 < BCl3 < CCl4
Solution
The covalent character increases with the polarization of the bond, which depends on the cation's charge density and the anion's polarizability. As we move from LiCl to CCl4, the covalent character increases due to decreasing ionic character.
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