Correct answer: $\frac{a}{b}$
For a conducting sphere, $V=\frac{1}{4\pi\varepsilon_0}\frac{Q}{R}$. If two spheres are at the same potential, then $Q\propto R$. Surface charge density is $\sigma=\frac{Q}{4\pi R^2}\propto \frac{1}{R}$. Hence, $\sigma_A/\sigma_B=b/a$? Wait, comparing carefully gives $\sigma_A/\sigma_B=\frac{b}{a}$ only if $Q$ is same; for equal potential, $Q\propto R$, so $\sigma\propto 1/R$, giving $\sigma_A/\sigma_B=\frac{b}{a}$.