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Which of the following complexes has CFSE = 0?
- Due to d5 configuration CFSE is zero.
- cis-platin
- [Cu(NH3)4]2+ hybridisation dsp2
- Cu2+ = 3d9 has one unpaired e−
Correct answer: Due to d5 configuration CFSE is zero.
Solution
A d5 configuration in a high-spin complex leads to equal distribution of electrons in t2g and eg orbitals, resulting in zero crystal field stabilization energy (CFSE).
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