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ExamsNEETChemistry

Which one of the following is an outer orbital complex and exhibits paramagnetic behaviour?

  1. [Ni(NH3)6]^2+
  2. [Zn(NH3)6]^2+
  3. [Cr(NH3)6]^3+
  4. [Co(NH3)6]^3+

Correct answer: [Cr(NH3)6]^3+

Solution

The complex [Cr(NH3)6]^3+ is an outer orbital complex because Cr^3+ has a 3d^3 configuration, and NH3 is a weak field ligand that does not cause pairing of electrons. This results in unpaired electrons, making the complex paramagnetic.

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