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For [Co(NH3)6]3+, Co3+ (27-3=24) has the configuration 3d6. What is the hybridization and magnetic property?
- sp3d2 (outer octahedral complex & paramagnetic)
- d2sp3 (inner octahedral complex & diamagnetic)
- sp3 (tetrahedral complex & paramagnetic)
- sp3d (outer octahedral complex & diamagnetic)
Correct answer: d2sp3 (inner octahedral complex & diamagnetic)
Solution
In [Co(NH3)6]3+, Co3+ has a 3d6 configuration. NH3 is a strong field ligand, causing pairing of electrons in the 3d orbitals. This results in a low-spin, inner d2sp3 hybridization and diamagnetic behavior.
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