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ExamsNEETChemistry

Which one of the following is an inner orbital complex as well as diamagnetic in behaviour? (Atomic number: Zn = 30, Cr = 24, Co = 27, Ni = 28)

  1. [Zn(NH3)6]2+
  2. [Cr(NH3)6]3+
  3. [Co(NH3)6]3+
  4. [Ni(NH3)6]2+

Correct answer: [Co(NH3)6]3+

Solution

The complex [Co(NH3)6]3+ is an inner orbital complex because Co3+ uses its 3d orbitals for hybridization (d2sp3) and is diamagnetic as all electrons are paired in the d-orbitals.

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