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ExamsJEE MainChemistry

In which of the following ionisation processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic?

  1. N2 → N2+
  2. C2 → C2+
  3. O2 → O2+
  4. NO → NO+

Correct answer: O2 → O2+

Solution

When O2 gains an electron, it becomes O2-, which is paramagnetic. However, when O2 loses an electron, it becomes O2+, which is diamagnetic. This is because the loss of an electron increases the bond energy and changes the magnetic behaviour.

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