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ExamsJEE MainChemistry

When N₂ is converted into N₂⁺, the dissociation energy of the N–N bond ______, and when O₂ is converted into O₂⁺, the dissociation energy of the O–O bond ______.

  1. increases, decreases
  2. decreases, increases
  3. decreases in both cases
  4. increases in both cases

Correct answer: decreases, increases

Solution

N2 -> N2+ removes a bonding electron, dropping bond order 3 -> 2.5, so the bond energy DECREASES. O2 -> O2+ removes an antibonding (pi*) electron, raising bond order 2 -> 2.5, so it INCREASES. Hence 'decreases, increases'.

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