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Match List-I with List-II. List-I (A) Solution of chloroform and acetone (B) Solution of ethanol and water (C) Solution of benzene and toluene (D) Solution of acetic acid in benzene List-II (i) Minimum boiling azeotrope (ii) Dimerizes (iii) Maximum boiling azeotrope (iv) ΔV_mix = 0

1. (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
2. (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
3. (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
4. (A)-(III), (B)-(IV), (C)-(IV), (D)-(I)

Correct answer: (A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Solution

The correct option matches each solution with its characteristic: chloroform and acetone form a maximum boiling azeotrope, ethanol and water exhibit no volume change upon mixing, benzene and toluene are ideal solutions with no significant interaction, and acetic acid dimerizes in benzene.

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