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ExamsJEE MainChemistry

Which reactant will give the following alcohol on reaction with one mole of phenyl magnesium bromide (PhMgBr) followed by acidic hydrolysis? Target alcohol: Ph2C(OH)CH3

  1. CH3 – C ≡ N
  2. Ph – C ≡ N
  3. CH3 – C(=O) – O – Ph
  4. Ph – C(=O) – CH3

Correct answer: Ph – C(=O) – CH3

Solution

The correct option, Ph – C(=O) – CH3, contains a carbonyl group that can react with phenyl magnesium bromide to form a tertiary alcohol after the addition of the Grignard reagent and subsequent acidic hydrolysis, resulting in the target alcohol structure.

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