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Which reagent can convert phenylmethyl ketone directly into ethylbenzene in a single step?
- LiAlH4
- Zn-Hg/HCl
- NaBH4
- CH3MgI
Correct answer: Zn-Hg/HCl
Solution
Acetophenone (PhCOCH3) is converted to ethylbenzene (PhCH2CH3) in one step by Clemmensen reduction (Zn-Hg/HCl), which reduces the carbonyl directly to a methylene. LiAlH4/NaBH4 stop at the alcohol.
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