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Lithium has a melting point of 181°C, which is nearly twice that of sodium at 98°C. This is mainly because
- as we move down the group, hydration energy falls
- as we move down the group, ionization energy falls
- as we move down the group, cohesive energy falls
- none of the above
Correct answer: as we move down the group, cohesive energy falls
Solution
Lithium has a higher melting point than sodium primarily due to its stronger cohesive energy, which is a result of its smaller atomic size and greater charge density, leading to stronger metallic bonding compared to sodium.
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