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ExamsJEE MainChemistry

Lithium has a melting point of 181°C, which is nearly twice that of sodium at 98°C. This is mainly because

  1. as we move down the group, hydration energy falls
  2. as we move down the group, ionization energy falls
  3. as we move down the group, cohesive energy falls
  4. none of the above

Correct answer: as we move down the group, cohesive energy falls

Solution

Lithium has a higher melting point than sodium primarily due to its stronger cohesive energy, which is a result of its smaller atomic size and greater charge density, leading to stronger metallic bonding compared to sodium.

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