Exams › JEE Main › Chemistry › Environmental Chemistry
90 questions with worked solutions.
Q1. When copper is left in moist air for a long time, it develops a green coating because of:
Answer: a layer of basic copper carbonate forming on the copper surface
Copper reacts with moisture and carbon dioxide in the air over time, leading to the formation of basic copper carbonate, which gives the characteristic green patina. This process is a result of copper's corrosion in the presence of these elements.
Q2. Why is chlorine commonly added during water treatment?
Answer: to destroy disease-causing microbes
Chlorine is added to water to kill disease-causing microorganisms (disinfection), not to raise dissolved oxygen.
Q3. Which of the following is classified as a primary pollutant?
Answer: CO
CO is a primary pollutant (emitted directly from incomplete combustion). H2SO4, PAN and aldehydes are secondary pollutants formed in the atmosphere, so the stored H2SO4 is wrong.
Answer: (ii) and (iv)
Carbon monoxide (CO) and oxides of nitrogen are harmful pollutants found in automobile exhaust, as they contribute to air pollution and can have serious health effects. In contrast, nitrogen (N2) is a non-toxic gas that makes up a large portion of the atmosphere, and methane (CH4) is not a direct product of combustion in typical vehicle exhaust.
Q5. If rainfall occurs together with a thunderstorm, the pH of the rainwater collected will be
Answer: a little lower than the pH of rainwater falling without a thunderstorm
Thunderstorms often produce more acidic rain due to the presence of lightning, which can convert nitrogen in the atmosphere into nitrogen oxides that dissolve in rainwater, lowering its pH compared to rain without a thunderstorm.
Q6. Photochemical smog is most likely to form during which condition?
Answer: summer in the daytime
Photochemical smog forms when sunlight triggers chemical reactions between pollutants, which is most prevalent during the summer when temperatures are higher and sunlight is abundant, particularly during the daytime.
Q7. The B.O.D. (biochemical oxygen demand) test is used to assess the level of
Answer: water contamination
The B.O.D. test measures the amount of oxygen consumed by microorganisms in water as they decompose organic matter, making it a key indicator of water contamination levels.
Q8. Smog is mainly due to the presence of which pair of gases?
Answer: Oxides of sulphur and nitrogen
Smog is caused by oxides of sulphur (classical) and nitrogen (photochemical), not by the oxygen and nitrogen of normal air.
Q9. Which statement correctly describes ozone-layer depletion?
Answer: Ozone depletion is more severe near the poles because ice crystals in polar clouds catalyze photochemical reactions that break down ozone through Cl• and ClO• radicals.
The correct option highlights that the unique conditions in polar regions, including the presence of ice crystals in polar stratospheric clouds, facilitate reactions that release chlorine radicals, which are highly effective in breaking down ozone molecules, leading to greater depletion compared to other areas.
Answer: aerosols and high-flying jets
The stratospheric ozone layer is endangered by chlorofluorocarbons from aerosols and by oxides of nitrogen from supersonic/high-flying jets. Pesticides do not deplete stratospheric ozone.
Q11. Thermal pollution primarily has its impact on which of the following?
Answer: aquatic organisms
Thermal pollution mainly affects aquatic organisms because it alters the temperature of water bodies, which can disrupt the delicate balance of ecosystems, harm fish and other aquatic life, and reduce oxygen levels in the water.
Q12. Sewage water is cleaned mainly by the action of
Answer: micro-organisms
Micro-organisms play a crucial role in the sewage treatment process by breaking down organic matter and pollutants, effectively purifying the water through biological decomposition.
Q13. Why is carbon monoxide (CO) dangerous to humans?
Answer: It binds to haemoglobin and competes with oxygen
CO is dangerous because it binds haemoglobin much more strongly than oxygen, forming carboxyhaemoglobin and starving tissues of O2. It is not a carcinogen.
Q14. Identify the statement that is incorrect.
Answer: Rainwater is termed acid rain when its pH is above 6.5.
Option D is incorrect because rainwater is classified as acid rain when its pH is below 5.6, not above 6.5, indicating a higher acidity level.
Q15. Repeated appearance of algal blooms in a lake is a sign of
Answer: high availability of nutrients
Recurrent algal blooms indicate a high availability of nutrients (N, P) - eutrophication. The stored 'no herbivores' is not the cause.
Q16. Which of the following is not usually present as a constituent of photochemical smog?
Answer: Chlorofluorocarbons
Photochemical smog contains ozone, PAN, acrolein, NOx and aldehydes. Chlorofluorocarbons are stratospheric pollutants, not smog constituents - so CFCs are the odd one out, not ozone (which is a major smog component).
Q17. Which of the following acts as a reservoir for carbon dioxide (CO2)?
Answer: Oceans
Oceans act as a significant reservoir for carbon dioxide because they absorb large amounts of CO2 from the atmosphere, helping to regulate global carbon levels and influence climate.
Answer: Fluorine
Mottled tooth enamel is caused by excess fluorine (fluoride) in drinking water (dental fluorosis), not boron.
Q19. Minamata disease results from contamination of which medium?
Answer: mercury from industrial effluents entering fishing waters
Minamata disease is caused by mercury poisoning, specifically from industrial waste that contaminates water bodies, leading to the accumulation of mercury in fish, which then affects human health when consumed.
Answer: FTFT
The correct option is right because statement (1) is false; acid rain is typically defined as rain with a pH below 5.6. Statement (2) is true as the ozone hole is indeed most pronounced during September–October. Statement (3) is false because methylcyclohexane does not deplete ozone; it is not an ozone-depleting substance. Statement (4) is true since COD is generally higher than BOD due to the inclusion of both biodegradable and non-biodegradable organic matter.
Q21. If rainfall occurs together with a thunderstorm, what happens to the pH of the collected rainwater?
Answer: It becomes slightly lower than the pH of rainwater falling without a thunderstorm
During a thunderstorm, lightning can produce nitrogen oxides, which dissolve in rainwater and form nitric acid, leading to a decrease in pH. This results in the rainwater being more acidic compared to rain that falls without a thunderstorm.
Q22. Smog is mainly due to the presence of which of the following?
Answer: Oxides of sulphur and nitrogen
Smog is primarily caused by the chemical reactions between oxides of sulfur and nitrogen, which are released from industrial processes and vehicle emissions, leading to the formation of particulate matter and other pollutants that contribute to smog.
Q23. Select the incorrect statement from the following set:
Answer: The ozone layer blocks infrared radiation from the Sun from reaching Earth
The ozone layer primarily absorbs harmful ultraviolet (UV) radiation, not infrared radiation, which is why this statement is incorrect.
Q24. Choose the statement that is not correct among the following.
Answer: Ozone is responsible for absorbing infrared radiation.
Ozone primarily absorbs ultraviolet radiation, not infrared radiation, making this statement incorrect.
Q25. DDT is classified as which of the following?
Answer: A pollutant that does not biodegrade readily
DDT is a synthetic pesticide that persists in the environment for long periods, accumulating in the tissues of living organisms and not breaking down easily, which classifies it as a pollutant.
Answer: Nitrate
Nitrate levels above 10 ppm can pose serious health risks, particularly for infants, as they can interfere with oxygen transport in the blood. The concentration of 100 ppm in this sample significantly exceeds safe drinking water standards, making it the primary concern.
Answer: Only F−
Fluoride (F−) at elevated levels can pose health risks, particularly to dental health, making the water sample unfit for drinking. While nitrate (NO3−) can also be harmful at high concentrations, the level of fluoride in this sample is specifically noted as a concern.
Answer: Mn
Manganese (Mn) at a concentration of 5.0 ppm exceeds the acceptable limits for drinking water, which can lead to health issues, making it the metal responsible for rendering the sample unfit for consumption.
Q29. What is the likely consequence of an excessive increase in atmospheric carbon dioxide levels?
Answer: rise in global temperatures
An excessive increase in atmospheric carbon dioxide levels enhances the greenhouse effect, trapping more heat in the Earth's atmosphere, which leads to a rise in global temperatures.
Answer: Both assertion and reason are correct, and the reason is the correct explanation for the assertion
The assertion is true because nitrogen and oxygen are indeed the primary gases in the atmosphere, and they typically do not react under normal conditions. The reason is also accurate, as the formation of nitrogen oxides requires high temperatures, such as those found in combustion processes, which explains why these gases do not react under standard atmospheric conditions.
Answer: Polluted water has BOD value higher than 10 ppm
BOD measures oxygen demand from organic pollution. Clean water has BOD <= 5 ppm, while polluted water has BOD higher than 10 ppm (often 17 ppm or more). Aerobic bacteria do not decrease BOD, and anaerobic bacteria do not increase it. So the correct statement is that polluted water has BOD value higher than 10 ppm.
Q32. The higher concentration of which gas in air can cause stiffness of flower buds ?
Answer: SO2
Sulfur dioxide (SO2) can lead to physiological stress in plants, causing symptoms such as stiffness in flower buds due to its toxic effects on plant tissues and disruption of normal growth processes.
Answer: Mn
Drinking-water limits (ppm): Fe ~0.3, Cu ~1-3, Zn ~5, but Mn ~0.05-0.1. Mn = 5.0 ppm exceeds its limit by ~50-100x, making the water unsuitable. Answer: Mn.
Q34. Air pollution that occurs in sunlight is: (1) oxidising smog (2) reducing smog (3) fog (4) acid rain
Answer: (1) oxidising smog
Oxidising smog, also known as photochemical smog, forms when sunlight reacts with pollutants like nitrogen oxides and volatile organic compounds, leading to the production of ozone and other harmful substances in the atmosphere.
Q35. The correct set of species responsible for the photochemical smog is:
Answer: NO, NO2, O3 and hydrocarbons
The correct option includes nitrogen oxides (NO and NO2), ozone (O3), and hydrocarbons, which are key components in the formation of photochemical smog through complex reactions driven by sunlight.
Answer: nitrogen oxides
Nitrogen oxides are the main contributors to the formation of photochemical smog, as they react with sunlight and volatile organic compounds to produce ozone and other harmful pollutants.
Answer: stratosphere
The region of the atmosphere from about 10 km to 50 km above sea level is the stratosphere (it contains the ozone layer); the mesosphere lies above it, roughly 50-85 km.
Answer: Using plastic bags
Using plastic bags is the environmentally harmful (wrong) practice. Restricting vehicle use, avoiding floodlighting, and composting are all responsible, eco-friendly actions.
Q39. The reaction that is NOT involved in the ozone layer depletion mechanism in the stratosphere is:
Answer: CH4 + 2O3 -> 3CH2 = O + 3H2O
ClO+O->Cl+O2, CF2Cl2 photolysis to Cl, and HOCl photolysis to OH+Cl are all genuine ozone-depletion steps. The reaction CH4 + 2O3 -> 3CH2=O + 3H2O (also unbalanced/fictitious) is not part of the mechanism.
Q40. The compound that is NOT a common component of photochemical smog is
Answer: CF2Cl2
Common photochemical-smog components include ozone (O3), PAN (CH3C(O)OONO2) and acrolein (CH2=CHCHO). CF2Cl2 is a chlorofluorocarbon refrigerant, not a smog constituent.
Q41. Thermal power plants can lead to-
Answer: Acid rain
Thermal power plants burn fossil fuels releasing SO2 and NOx, which form sulfuric and nitric acids in the atmosphere, causing acid rain.
Answer: (2) (c) and (d)
Statements (c) 'cannot cause respiratory ailments' and (d) 'not harmful for trees' are false, since acid rain causes respiratory problems and damages vegetation; (a) corroding pipes and (b) damaging stone are true. So the incorrect statements are (c) and (d).
Q43. The condition that indicates a polluted environment is
Answer: eutrophication
BOD of 5 ppm, 0.03% CO2, and rain pH 5.6 are all normal/clean conditions. Eutrophication (nutrient over-enrichment causing algal blooms and oxygen depletion) is the indicator of a polluted environment. Correct option: eutrophication.
Answer: (a), (b), (c) and (e)
Carbon dioxide (CO2), water vapor (H2O), chlorofluorocarbons (CFCs), and ozone (O3) are all known to trap heat in the atmosphere, contributing to the greenhouse effect, while oxygen (O2) does not have this property.
Answer: (3)
Biochemical Oxygen Demand (BOD) specifically measures the amount of oxygen that bacteria require to decompose organic matter in a water sample, making option (3) the correct choice.
Answer: Both statement I and Statement II are false
Both statements are incorrect because the primary allotrope of oxygen involved in smog formation is ozone, which is not a direct intermediate in reducing smog, and while nitrogen oxides and sulfur oxides do contribute to smog, they are more associated with traditional smog rather than photochemical smog.
Answer: Both Statement I and Statement II are true.
Rainwater typically has a pH of around 5.6 due to the presence of dissolved carbon dioxide, which forms carbonic acid. When the pH falls below this level, it indicates an increase in acidity, thus classifying it as acid rain.
Q48. Which one of the following statements is NOT correct ?
Answer: Eutrophication leads to increase in the oxygen level in water
Eutrophication typically results in an overgrowth of algae, which can deplete oxygen levels in the water as the algae die and decompose, leading to hypoxic or anaerobic conditions rather than an increase in oxygen.
Answer: (a) - (iii), (b) - (iv), (c) - (i), (d) - (ii)
CO binds haemoglobin (iii); SO2 causes stiffness of flower buds (iv); polychlorinated biphenyls are carcinogenic (i); oxides of nitrogen are metabolized by Pyrus plants (ii). So (a)-iii,(b)-iv,(c)-i,(d)-ii (index 0).
Q50. BOD values (in ppm) for clean water (A) and polluted water (B) are expected respectively:
Answer: A < 5, B > 17
Clean water typically has very low BOD values, indicating minimal organic pollution, while polluted water has higher BOD values due to the presence of organic matter that consumes oxygen.