According to molecular orbital theory, what is the ratio of the number of pi electrons in C2 to that in B2?
1:1
2:1
1:2
3:2
Correct answer: 2:1
Solution
In B2 (6 valence-region electrons in this scheme) 2 electrons occupy pi(2p) orbitals, while in C2 all 4 bonding electrons occupy the pi(2p) orbitals, giving a pi-electron ratio of 4:2 = 2:1.