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ExamsJEE AdvancedChemistry

Statement 1: The standard reduction potentials (SRP) of three metal ions A⁺, B²+, and C³+ are -0.3 V, -0.5 V, and 0.8 V respectively. Therefore, the oxidising power order is: C³+ > A⁺ > B²+. Statement 2: A higher SRP corresponds to a stronger oxidising agent.

  1. Statement 1 is true, Statement 2 is true, and Statement 2 is the correct explanation of Statement 1.
  2. Statement 1 is true, Statement 2 is true, but Statement 2 is NOT the correct explanation of Statement 1.
  3. Statement 1 is true, Statement 2 is false.
  4. Statement 1 is false, Statement 2 is true.

Correct answer: Statement 1 is true, Statement 2 is true, and Statement 2 is the correct explanation of Statement 1.

Solution

Statement 2 is correct: higher SRP means the ion is more easily reduced, hence a stronger oxidising agent. Ranking by SRP: C³+(0.8 V) > A^+(-0.3 V) > B²+(-0.5 V), confirming Statement 1. Statement 2 directly explains Statement 1.

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