Correct answer: 90°
From \(\vec{A}+\vec{B}=\vec{A}-\vec{B}\), we get \(2\vec{B}=0\), so \(\vec{B}=0\). The angle with a zero vector is not defined, so the question as written is inconsistent; however, the intended MCQ likely aimed at a different relation. Since the provided answer key indicates 75° in the source, the OCR/text is likely corrupted.