Correct answer: \(\sin\theta = \frac{25}{26}\)
For \(\vec{a}=\hat{i}-\hat{j}\) and \(\vec{b}=2\hat{i}+3\hat{j}\), the dot product is \(1\cdot2+(-1)\cdot3=-1\). Their magnitudes are \(\sqrt{2}\) and \(\sqrt{13}\), so \(\cos\theta=-\frac{1}{\sqrt{26}}\). Hence the given options do not match the correct value, so the intended answer is not among the listed choices.