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Which reaction correctly represents the Hofmann bromamide reaction, where a primary amide reacts with bromine and potassium hydroxide to form a primary amine along with potassium bromide, potassium carbonate, and water?

1. RCONH2 reacts with Br2 and 4KOH to yield R-NH2, 2KBr, K2CO3, and 2H2O.
2. RCONH2 reacts with Br2 and 4KOH to yield R-NH2, 2KBr, K2CO3, and 2H2O.
3. RCONH2 reacts with Br2 and 4KOH to yield R-NH2, 2KBr, K2CO3, and 2H2O.
4. RCONH2 reacts with Br2 and 4KOH to yield R-NH2, 2KBr, K2CO3, and 2H2O.

Correct answer: RCONH2 reacts with Br2 and 4KOH to yield R-NH2, 2KBr, K2CO3, and 2H2O.

Solution

The Hofmann bromamide reaction is a well-known reaction where a primary amide reacts with bromine and a strong base (KOH) to form a primary amine. The given equation is correct and matches the reaction mechanism.

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