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ExamsNEETChemistry

The correct statement regarding the basicity of arylamines is

  1. Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π electron system.
  2. Arylamines are generally more basic than alkylamines because the nitrogen lone-pair electrons are not delocalized by interaction with the aromatic ring π electron system.
  3. Arylamines are generally more basic than alkylamines because of aryl group.
  4. Arylamines are generally more basic than alkylamines, because the nitrogen atom in arylamines is sp-hybridized.

Correct answer: Arylamines are generally less basic than alkylamines because the nitrogen lone-pair electrons are delocalized by interaction with the aromatic ring π electron system.

Solution

Arylamines are less basic than alkylamines because the lone pair of electrons on the nitrogen atom in arylamines is delocalized into the aromatic ring, reducing its availability for protonation.

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