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Match the compounds given in List-I with List-II and select the suitable option using the code given below: List I: (A) Benzaldehyde (B) Phthalic anhydride (C) Phenyl benzoate (D) Methyl salicylate List II: (i) Phenolphthalein (ii) Benzoin condensation (iii) Oil of wintergreen (iv) Fries rearrangement Code:

1. (a) (A) (iv), (B) (ii), (C) (iii), (D) (i)
2. (b) (A) (ii), (B) (iii), (C) (iv), (D) (i)
3. (c) (A) (ii), (B) (iii), (C) (i), (D) (iv)
4. (d) (A) (ii), (B) (iv), (C) (iii), (D) (i)

Correct answer: (d) (A) (ii), (B) (iv), (C) (iii), (D) (i)

Solution

Benzaldehyde undergoes benzoin condensation (ii), phthalic anhydride is used in the synthesis of phenolphthalein (i), phenyl benzoate undergoes Fries rearrangement (iv), and methyl salicylate is known as oil of wintergreen (iii).

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