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ExamsNEETChemistry

A solution contains non-volatile solute of molecular mass M₂. Which of the following can be used to calculate the molecular mass of solute in terms of osmotic pressure?

  1. M₂ = (m₂/V)RT
  2. M₂ = (m₂/V)RT
  3. M₂ = (m₂/V)RT
  4. M₂ = (m₂/V)πRT

Correct answer: M₂ = (m₂/V)RT

Solution

The molecular mass of the solute can be calculated using the formula derived from the osmotic pressure equation: π = (n₂/V)RT, where n₂ = m₂/M₂. Rearranging gives M₂ = (m₂/V)RT/π.

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