Correct answer: Al₂(SO₄)₃
Freezing point depression depends on the van 't Hoff factor (i), which is the number of particles a compound dissociates into in solution. Al₂(SO₄)₃ dissociates into 5 ions (2 Al³⁺ and 3 SO₄²⁻), the highest among the options, leading to the largest freezing point depression.