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CaF₂ ⇌ Ca²⁺ + 2F⁻. Due to common ion effect of NaF, solubility of CaF₂ is further suppressed. Therefore, the concentration of F⁻ will be mainly due to NaF.

  1. Ksp = [Ca²⁺][F⁻]²
  2. Ksp = [Ca²⁺][F⁻]
  3. Ksp = [Ca²⁺][F⁻]³
  4. Ksp = [Ca²⁺][F⁻]⁴

Correct answer: Ksp = [Ca²⁺][F⁻]²

Solution

The solubility product (Ksp) for CaF₂ is defined as the product of the concentrations of its dissociated ions, with the stoichiometric coefficients as exponents. Since CaF₂ dissociates into one Ca²⁺ and two F⁻ ions, Ksp = [Ca²⁺][F⁻]².

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