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ExamsNEETChemistry

Calculate the ratio of \( H C O O^{-} \) and \( F^{-} \) in a mixture of \( 0.2 M \) HCOOH \( \left(K_{a}=\right. \) \( \left.2 \times 10^{-4}\right) \) and \( 0.1 M H F\left(K_{a}=6.6 \times\right. \) \( \left.10^{-4}\right) \)

  1. 1: 6.6
  2. 1: 3.3
  3. 2: 3.3
  4. 3.3 : 2

Correct answer: 1: 3.3

Solution

For each weak acid, the conjugate base formed is proportional to its dissociation, so [HCOO^-]/[HCOOH]  and [F^-]/[HF]  can be estimated from Ka and initial concentration. Comparing those two ratios gives the relative amounts of HCOO^-  and F^- , which simplifies to 1:3.3.

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