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Which of the following statements about pH and H⁺ ion concentration is incorrect?
- Addition of one drop of concentrated HCl in NH₄OH solution decreases pH of the solution.
- A solution of the mixture of one equivalent of each of CH₃COOH and NaOH has a pH of 7.
- pH of pure neutral water is not zero.
- A cold and concentrated H₂SO₄ has lower H⁺ ion concentration than a dilute solution of H₂SO₄.
Correct answer: A cold and concentrated H₂SO₄ has lower H⁺ ion concentration than a dilute solution of H₂SO₄.
Solution
Cold and concentrated H₂SO₄ has a higher H⁺ ion concentration than a dilute solution due to its high dissociation in water. Thus, option D is incorrect.
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