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The ionization constant of ammonium hydroxide is 1.77 × 10⁻⁵ at 298 K. Hydrolysis constant of ammonium chloride is:
- 6.50 × 10⁻⁶
- 5.65 × 10⁻¹³
- 5.65 × 10⁻¹²
- 5.65 × 10⁻¹⁰
Correct answer: 5.65 × 10⁻¹²
Solution
The hydrolysis constant (Kh) is related to the ionization constant (Kb) of ammonium hydroxide by the relation Kh = Kw / Kb, where Kw = 1 × 10⁻¹⁴ at 298 K. Substituting Kb = 1.77 × 10⁻⁵, we get Kh = 1 × 10⁻¹⁴ / 1.77 × 10⁻⁵ = 5.65 × 10⁻¹².
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