StreakPeaked· Practice

ExamsNEETChemistry › Benzene and its Derivatives

NEET Chemistry: Benzene and its Derivatives questions with solutions

1 questions with worked solutions.

Questions

Q1. The correct order of decreasing acidity of nitrophenols will be:

  1. \( m- \) nitrophenol \( >p- \) nitrophenol \( >o \) - nitrophenol
  2. \( o \) - nitrophenol \( >m- \) nitrophenol \( >p- \) nitrophenol
  3. \( p- \) nitrophenol \( >m- \) nitrophenol \( >o- \) nitrophenol
  4. \( p- \) nitrophenol \( >o \) - nitrophenol \( >m- \) nitrophenol

Answer: \( o \) - nitrophenol \( >m- \) nitrophenol \( >p- \) nitrophenol

Ortho-nitrophenol is most acidic because the nitro group strongly withdraws electron density and can stabilize the conjugate base effectively. Meta lacks resonance stabilization, so it is less acidic than ortho, while para is least acidic here due to relative stabilization differences and intramolecular effects in the ortho isomer.

⚔️ Practice NEET Chemistry free + battle 1v1 →