Correct answer: (1/(4*pi*epsilon₀)) * (2qQ/a) * (1 - 1/sqrt(5))
Place the square with side 2a. The two +q charges are at the ends of side 1; the two -q charges at the far corners. At the centre, every charge is distance a*sqrt(2) away and the +q and -q contributions cancel, so V_centre = 0. At the midpoint of side 1: distance to each +q is a (so V from both +q = 2*kq/a), distance to each -q is sqrt((2a)² + a²) = a*sqrt(5) (so V from both -q = -2*kq/(a*sqrt(5))). Hence V_mid = (2kq/a)(1 - 1/sqrt(5)). KE at centre = Q*(V_mid - V_centre) = Q*(2kq/a)(1 - 1/sqrt(5)) = (1/(4*pi*epsilon₀))*(2qQ/a)*(1 - 1/sqrt(5)).