Correct answer: 1
For any conductor system, the charge appearing on the outermost surface equals the algebraic sum of all enclosed charges = total charge. Before connection, the outer surface of the outer sphere carries 2 + 4 = 6 C. After connecting with a wire, the inner sphere's charge flows to the outer sphere, but the total is still 6 C, so the outermost surface still carries 6 C. The ratio is 6/6 = 1.