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ExamsJEE MainChemistry

State whether the following is true or false: In aqueous solution, Cu+ undergoes disproportionation to give Cu2+ and metallic copper.

  1. True
  2. False
  3. Only at high temperature
  4. Only in non-aqueous medium

Correct answer: True

Solution

Cu+ is unstable in water because the large hydration energy of Cu2+ more than compensates the second ionisation energy, making 2Cu+ -> Cu2+ + Cu spontaneous.

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