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ExamsJEE MainChemistry

In the following sets of reactants which two sets best exhibit the amphoteric character of Al2O3·xH2O ? Set I Al2O3·xH2O(s) + OH−(aq) Set II Al2O3·xH2O(s) + H2O(l) Set III Al2O3·xH2O(s) + H+(aq) Set IV Al2O3·xH2O(s) + NH3(aq)

  1. 2 and 4
  2. 1 and 2
  3. 1 and 3
  4. 3 and 4

Correct answer: 1 and 3

Solution

Al2O3·xH2O can act as both an acid and a base, which is the definition of amphoteric behavior. In Set I, it reacts with hydroxide ions (acting as an acid), and in Set III, it reacts with hydrogen ions (acting as a base), demonstrating its ability to interact with both types of reactants.

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