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ExamsJEE MainChemistry

Arrange the following carbocations in the decreasing order of stability I. p-Br–C6H4–CH2+ II. C6H5–CH2+ III. p-CH3O–C6H4–CH2+ IV. p-CHO–C6H4–CH2+ V. p-CH3–C6H4–CH2+ Choose the correct answer from the options given below:

  1. I > II > IV > V > III
  2. I > IV > II > V > III
  3. IV > I > II > V > III
  4. IV > II > I > III > V

Correct answer: IV > I > II > V > III

Solution

The stability of carbocations is influenced by the electron-donating or withdrawing effects of substituents on the aromatic ring. In this case, the p-CHO group is a strong electron-withdrawing group, making the carbocation less stable, while the p-CH3O and p-CH3 groups are electron-donating, enhancing stability. Thus, the order of stability is determined by the strength of these effects, leading to the correct arrangement.

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