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ExamsJEE MainChemistry

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R Assertion A : In TlI3, isomorphous to CsI3, the metal is present in +1 oxidation state. Reason R : Tl metal has fourteen f electrons in the electronic configuration. In the light of the above statements, choose the most appropriate answer from the options given below :

  1. A is correct but R is not correct
  2. Both A and R are correct and R is the correct explanation of A.
  3. A is not correct but R is correct
  4. Both A and R are correct but R is NOT the correct explanation of A.

Correct answer: A is correct but R is not correct

Solution

Assertion A is correct because thallium (Tl) in TlI3 is indeed in the +1 oxidation state. However, Reason R is incorrect as thallium does not have fourteen f electrons; it has a different electron configuration that does not support the claim made in R.

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