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For the Balmer series in the spectrum of H atom, \(\bar{\nu} = R_H\left\{\frac{1}{n_1^2}-\frac{1}{n_2^2}\right\}\), the correct statements among (I) to (IV) are : (I) As wavelength decreases, the lines in the series converge (II) The integer n1 is equal to 2 (III) The lines of longest wavelength corresponds to n2 = 3 (IV) The ionization energy of hydrogen can be calculated from wave number of these lines (1) (II), (III), (IV) (2) (I), (III), (IV) (3) (I), (II), (III) (4) (I), (II), (IV)
- (1) (II), (III), (IV)
- (2) (I), (III), (IV)
- (3) (I), (II), (III)
- (4) (I), (II), (IV)
Correct answer: (2) (I), (III), (IV)
Solution
The correct option includes statements that accurately describe the Balmer series: as the wavelength decreases, the spectral lines converge due to higher energy transitions, the longest wavelength corresponds to the transition from n=3 to n=2, and the ionization energy can indeed be derived from the wave numbers of these transitions.
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