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ExamsJEE MainChemistry

A lithium ion and a proton are each accelerated through the same potential difference. If their de Broglie wavelengths are λ₁ and λ₂, respectively, and m_(Li) = 9mₚ, what is the ratio λ₁: λ₂?

  1. 1: 2
  2. 1: 4
  3. 1: 1
  4. 1: 3√(3)

Correct answer: 1: 3√(3)

Solution

The de Broglie wavelength is inversely proportional to the momentum of a particle, which depends on its mass and velocity. Since the lithium ion has a mass 9 times that of the proton and both are accelerated through the same potential difference, the proton will have a higher velocity and thus a shorter wavelength, leading to the ratio of their wavelengths being 1: 3√3.

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