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Ice and water are placed in a closed container at a pressure of 1 atm and temperature 273.15 K. If pressure of the system is increased 2 times, keeping temperature constant, then identify correct observation from following:
(1) Volume of system increases.
(2) Liquid phase disappears completely.
(3) The amount of ice decreases.
(4) The solid phase (ice) disappears completely.
- (1), (2) and (3)
- (2) and (4)
- (1) and (4)
- (4)
Correct answer: (4)
Solution
Increasing the pressure while keeping the temperature constant will favor the liquid phase over the solid phase in a system containing ice and water. At 273.15 K, the solid phase (ice) will disappear completely as the pressure increases, leading to a complete transition to the liquid phase.
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