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ExamsJEE MainChemistry

The equation which is balanced and represents correct product(s) is:

  1. Li2O + 2KCl → 2LiCl + K2O
  2. [CoCl(NH3)5] + 5H+ → Co2+ + 5NH4+ + Cl−
  3. [Mg(H2O)6]2+ + (EDTA)4− —excess NaOH→ [Mg(EDTA)]2− + 6H2O
  4. CuSO4 + 4KCN → K2[Cu(CN)4] + K2SO4

Correct answer: [Mg(H2O)6]2+ + (EDTA)4− —excess NaOH→ [Mg(EDTA)]2− + 6H2O

Solution

[Mg(H2O)6]^2+ + (EDTA)^4- -> [Mg(EDTA)]^2- + 6H2O is correctly balanced in mass and charge (-2 = -2) and is a genuine complexometric reaction. The Li2O/KCl swap does not occur, the [CoCl(NH3)5] equation is charge-unbalanced, and CuSO4 + KCN gives Cu(I) as K3[Cu(CN)4], not K2[Cu(CN)4].

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