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Larger number of oxidation states are exhibited by the actinoids than those by the lanthanoids, the main reason being
- 4f orbitals more diffused than the 5f orbitals
- lesser energy difference between 5f and 6d than between 4f and 5d
- more energy difference between 5f and 6d than between 4f and 5d
- more reactive nature of the actinoids than the lanthanoids
Correct answer: lesser energy difference between 5f and 6d than between 4f and 5d
Solution
In actinoids the 5f, 6d and 7s orbitals are close in energy (small 5f-6d gap), so more electrons take part in bonding, giving a larger range of oxidation states than the lanthanoids where the 4f-5d gap is larger.
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